Form 4 Chemistry Practice Paper: Atomic Structure, Periodic Table and Bonding
- 2026-11-05
Form 4 Chemistry – 12 questions – 100 marks – 75 minutes
Form 4 Chemistry paper: 12 questions, 100 marks, 75 minutes covering atomic structure, isotopes, ionic and covalent bonding, electron configuration and periodic table trends.
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Paper details Form 4 Chemistry practice paper with 12 structured questions on atoms, isotopes, bonding and the periodic table; includes full worked answers and two printable PDFs.
Section A: Atomic Structure and Isotopes (Q1-Q3)
Answer all questions; show the expression, substitution and unit for every calculation.
| # | Question | Answer and marking notes |
|---|---|---|
| 1 | An atom X has atomic number (Z) 17 and mass number (A) 35. (a) State the number of protons, neutrons and electrons. (b) Write the electron configuration of the atom. |
(a) Protons = 17, neutrons = 35 – 17 = 18, electrons = 17. (b) Electron configuration: 2, 8, 7. Marking notes: protons (2 marks), neutrons (2 marks), electrons (2 marks), electron configuration (2 marks). |
| 2 | Chlorine has two isotopes, 35Cl and 37Cl, with abundances of 75% and 25%. Calculate the relative atomic mass of chlorine. | Relative atomic mass = 0.75 x 35 + 0.25 x 37 = 26.25 + 9.25 = 35.5. Marking notes: correct expression (3 marks), correct substitution of abundances (3 marks), answer with sensible significant figures (2 marks). |
| 3 | Magnesium (Z = 12) reacts with oxygen (Z = 8) to form magnesium oxide. (a) Write the electron configuration of the magnesium ion and the oxide ion. (b) State which noble gas has the same number of electrons as these ions. |
(a) A magnesium atom loses 2 electrons to form the magnesium ion, configuration 2, 8 (10 electrons). An oxygen atom gains 2 electrons to form the oxide ion, configuration 2, 8 (10 electrons). (b) Both ions have 10 electrons, the same as neon (Ne, Z = 10). Marking notes: magnesium ion configuration (3 marks), oxide ion configuration (3 marks), naming neon (3 marks). |
| 4 | Explain how ionic bonding is formed in sodium chloride (NaCl), and explain why sodium chloride has a high melting point. | A sodium atom (2, 8, 1) transfers its single outermost electron to a chlorine atom (2, 8, 7), forming Na+ and Cl- ions. The strong electrostatic attraction between oppositely charged ions is the ionic bond, and it holds the ions in a giant ionic lattice. Melting requires breaking many strong electrostatic attractions, so a large amount of energy is needed and the melting point is high. Marking notes: electron transfer (3 marks), ions and ionic bond (2 marks), lattice and melting point (3 marks). |
Section B: Bonding and Formulae (Q4-Q8)
Relative atomic masses: H = 1, C = 12, N = 14, O = 16, S = 32, Ca = 40; Avogadro constant = 6.02 x 10^23 per mol.
| # | Question | Answer and marking notes |
|---|---|---|
| 5 | State the number of shared electron pairs in a water molecule (H2O), an ammonia molecule (NH3) and a methane molecule (CH4), and give the total. | Water has 2 shared pairs (two O-H single bonds); ammonia has 3 shared pairs; methane has 4 shared pairs. Total = 2 + 3 + 4 = 9 pairs. Marking notes: water (2 marks), ammonia (2 marks), methane (2 marks), total (2 marks). |
| 6 | An element Y has atomic number 16. (a) Write the electron configuration of a Y atom. (b) State the group and period of Y in the periodic table. (c) State the number of outermost shell electrons in a Y atom. |
(a) Electron configuration: 2, 8, 6. (b) There are 6 outermost electrons, so Y is in Group VI (Group 16); it has 3 occupied shells, so it is in Period 3. (c) The number of outermost shell electrons is 6. Marking notes: electron configuration (3 marks), group and period (3 marks), outermost electrons (3 marks). |
| 7 | Write the chemical formulae of aluminium oxide, calcium chloride and sodium sulphate. | Aluminium oxide: the lowest common multiple of the charges of Al3+ and O2- is 6, so the formula is Al2O3. Calcium chloride: Ca2+ combines with Cl- in the ratio 1:2, giving CaCl2. Sodium sulphate: Na+ combines with SO4 2- in the ratio 2:1, giving Na2SO4. Marking notes: aluminium oxide (3 marks), calcium chloride (2 marks), sodium sulphate (3 marks). |
| 8 | Calculate the relative molecular masses of H2SO4 and Ca(OH)2. (H = 1, O = 16, S = 32, Ca = 40) | H2SO4: 2 x 1 + 32 + 4 x 16 = 2 + 32 + 64 = 98. Ca(OH)2: 40 + 2 x (16 + 1) = 40 + 34 = 74. Marking notes: H2SO4 working (3 marks), H2SO4 answer (1 mark), Ca(OH)2 working (3 marks), Ca(OH)2 answer (1 mark), no unit stated (1 mark). |
Section C: Mole Calculations and Structure (Q9-Q12)
Answer explanation questions in full sentences; give numerical answers to sensible significant figures.
| # | Question | Answer and marking notes |
|---|---|---|
| 9 | Find the mass of 0.25 mol of carbon dioxide (CO2) and the number of molecules it contains. (C = 12, O = 16, Avogadro constant = 6.02 x 10^23 per mol) | Molar mass = 12 + 2 x 16 = 44 g/mol. Mass = 0.25 x 44 = 11.0 g. Number of molecules = 0.25 x 6.02 x 10^23 = 1.505e+23, that is 1.505 x 10^23 molecules. Marking notes: molar mass (3 marks), mass with unit (3 marks), number of molecules (2 marks). |
| 10 | Calculate the percentage by mass of nitrogen in ammonium nitrate (NH4NO3). (N = 14, H = 1, O = 16) | Molar mass = 2 x 14 + 4 x 1 + 3 x 16 = 28 + 4 + 48 = 80 g/mol. Percentage by mass of nitrogen = 28 / 80 x 100% = 35.0%. Marking notes: molar mass (5 marks), percentage expression and answer (4 marks). |
| 11 | An ion X2+ contains 18 electrons. (a) Find the atomic number of element X. (b) Write the electron configuration of a X atom. |
(a) A X atom has 18 + 2 = 20 electrons, so the atomic number is 20 (calcium). (b) Electron configuration: 2, 8, 8, 2. Marking notes: deducing the number of electrons (4 marks), electron configuration (4 marks). |
| 12 | Explain why graphite conducts electricity but diamond does not. | Graphite and diamond are both giant covalent structures of carbon, but their bonding differs. In graphite each carbon atom bonds to only 3 other carbon atoms, leaving one valence electron free to move between the layers (a delocalised electron), so graphite conducts electricity. In diamond each carbon atom bonds to 4 carbon atoms, so all 4 valence electrons are fixed in covalent bonds and there are no free electrons; diamond therefore does not conduct. Marking notes: delocalised electrons in graphite (4 marks), all electrons bonded in diamond (4 marks). |
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