S5 Chemistry Electrolysis, Paper 4: charge, gas volume and time
- 2026-11-02
S5 Chemistry Electrolysis, Paper 4: charge, gas volume and time
Ten graded items from Q equals I t to metal masses, gas volumes and the time a current must flow.
Focus Fix the units before computing charge; divide by the ion charge for metals, use two electrons per hydrogen molecule, and divide by current only at the end.
01 Paper details (check answers afterwards)
| Item | Detail |
|---|---|
| Questions | 10 |
| Suggested time | 25 |
| Difficulty mix | Foundation 4 · Intermediate 3 · Challenge 2 · Error redo 1 |
| Chapter | Chapter: S5 Chemistry: Electrolysis |
| Level | Four basic, three advanced, two challenge and one error-repair item |
02 Questions (10 items)
- FoundationA current of 1.0 A flows for 100 s. Find the charge passed.
- FoundationAt which electrode does reduction occur during electrolysis?
- FoundationWhat material is normally used for the anode in electroplating?
- FoundationWhich gas forms at the anode when dilute sulphuric acid is electrolysed?
- IntermediateCopper sulphate solution is electrolysed at 0.50 A for 19 300 s. Find the mass of copper deposited, with Cu as 63.5.
- IntermediateHow many dm^3 of hydrogen could be released at the cathode by 0.20 mol of electrons, taking the molar volume as 24 dm^3?
- IntermediateWhat forms at the cathode when molten sodium chloride and aqueous sodium chloride are electrolysed?
- ChallengeSilver nitrate solution is electrolysed at 3.0 A for 3 860 s. Find the mass of silver deposited, with Ag as 107.9.
- ChallengeHow long must 2.0 A flow to deposit 1.00 g of copper, with Cu as 63.5 and F as 96 500?
- Error redoA student says electrons travel through the electrolyte so the solution conducts. What is wrong?
03 Answers and one-line notes
| # | Answer | One-line note |
|---|---|---|
| 1 | 100 C | Charge is current times time, so 1.0 times 100 gives 100 coulombs. |
| 2 | The cathode | The cathode gains electrons, and gaining electrons is the definition of reduction. |
| 3 | The pure metal being plated | The anode dissolves to replace the metal ions in the bath, so the pure plating metal keeps the concentration steady. |
| 4 | Oxygen | Hydroxide ions discharge at the anode to give oxygen, while hydrogen forms at the cathode. |
| 5 | 3.18 g | 9 650 coulombs is 0.10 mol of electrons, and a divalent ion takes half of that, giving 3.18 grams. |
| 6 | 2.4 dm^3 | Two electrons give one hydrogen molecule, so 0.10 mol of gas forms and occupies 2.4 dm^3. |
| 7 | Sodium from the melt, hydrogen from the solution | In aqueous solution hydrogen ions discharge more readily than sodium ions, so hydrogen forms instead of sodium. |
| 8 | 12.95 g | 11 580 coulombs is 0.12 mol of electrons, and silver is monovalent so 0.12 mol deposits 12.95 grams. |
| 9 | About 1 520 s | 1.00 gram of copper is 0.0157 mol, needing 0.0315 mol of electrons or 3 039 coulombs, which at 2.0 A takes about 1 520 seconds. |
| 10 | Electrons stay in the electrodes and wires; ions carry the current inside the solution | Electrons stay in the electrodes and the external circuit; inside the solution the current is carried by migrating ions. |
04 What to do after marking
- After marking, redo only the wrong items and write down which step went wrong (formula, unit, or misread number).
- Repeat the same item two days later; move to the next paper only when both attempts are correct.
- Parents only need the answer and note columns; there is no need to explain every item.
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