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S5 Chemistry Titration and pH, Paper 1: neutralising volumes, dilution and titration means

S5 Chemistry Titration and pH, Paper 1: neutralising volumes, dilution and titration means

  • 2026-11-02

S5 Chemistry Titration and pH, Paper 1: neutralising volumes, dilution and titration means

Ten graded items from one-to-one neutralisation through diprotic acids, dilution factors and titration readings, each with an answer.

Focus Discard wild titration readings before averaging; a diprotic acid releases two hydrogen ions; dilution keeps the moles constant.

01 Paper details (check answers afterwards)

Item Detail
Questions 10
Suggested time 25
Difficulty mix Foundation 4 · Intermediate 3 · Challenge 2 · Error redo 1
Chapter Chapter: S5 Chemistry: Acid-Base Titration and pH
Level Four basic, three advanced, two challenge and one error-repair item

02 Questions (10 items)

  1. FoundationWhat volume of 0.100 mol dm^-3 hydrochloric acid neutralises 25.0 cm^3 of 0.100 mol dm^-3 sodium hydroxide?
  2. FoundationWhat is the pH of 0.010 mol dm^-3 hydrochloric acid?
  3. FoundationWhat is the pH of 0.010 mol dm^-3 sodium hydroxide at 25 C?
  4. FoundationAt the end point of a titration, when does the indicator change colour?
  5. IntermediateWhat volume of 0.100 mol dm^-3 sulphuric acid neutralises 20.0 cm^3 of 0.150 mol dm^-3 sodium hydroxide?
  6. IntermediateWhat is the pH after 0.10 mol dm^-3 hydrochloric acid is diluted a hundredfold?
  7. IntermediateWhat is the pH of 0.0050 mol dm^-3 sulphuric acid, a fully ionised diprotic acid?
  8. Challenge25.0 cm^3 of hydrochloric acid of unknown concentration needs 22.30, 22.40 and 22.50 cm^3 of 0.100 mol dm^-3 sodium hydroxide. Find the acid concentration.
  9. ChallengeWhat volume of 0.100 mol dm^-3 hydrochloric acid reacts completely with 0.250 g of calcium carbonate of molar mass 100 g mol^-1?
  10. Error redoError repair: a student averages 24.10, 24.20 and 26.50 cm^3 to get 24.93 cm^3. What is the correct mean?

03 Answers and one-line notes

# Answer One-line note
1 25.0 cm^3 Sodium hydroxide and hydrochloric acid react one to one, so equal concentrations need equal volumes.
2 pH 2.00 A strong acid ionises fully, so the hydrogen ion concentration is 0.010 and the pH is 2.00.
3 pH 12.00 The hydroxide concentration is 0.010, so pOH is 2.00 and pH is 14 minus 2.00.
4 At the last drop of standard solution, when the pH changes sharply The end point is the instant of exact neutralisation, when the indicator changes colour.
5 15.0 cm^3 There is 0.00300 mol of alkali; a diprotic acid needs half that, so 0.00150 mol divides by 0.100 to give 15.0 cm^3.
6 pH 3.00 Diluting a hundredfold lowers the hydrogen ion concentration to 0.0010, so pH rises from 1.00 to 3.00.
7 pH 2.00 Each molecule releases two hydrogen ions, giving 0.010, and the negative logarithm is 2.00.
8 0.0896 mol dm^-3 The three readings agree, averaging 22.40 cm^3 or 0.002240 mol, which divides by 0.0250 dm^3 to give 0.0896.
9 50.0 cm^3 0.00250 mol of calcium carbonate needs 0.00500 mol of acid, which divides by 0.100 to give 0.0500 dm^3.
10 24.15 cm^3 The reading 26.50 is wild and must be discarded, so the mean of the other two is 24.15 cm^3.

04 What to do after marking

  • After marking, redo only the wrong items and write down which step went wrong (formula, unit, or misread number).
  • Repeat the same item two days later; move to the next paper only when both attempts are correct.
  • Parents only need the answer and note columns; there is no need to explain every item.

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