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S6 Chemistry: Organic Reactions and Isomerism (Paper 2: intermediate)

S6 Chemistry: Organic Reactions and Isomerism (Paper 2: intermediate)

  • 2026-11-12

S6 Chemistry: Organic Reactions and Isomerism (Paper 2: intermediate)

Ten intermediate items on isomer counts for pentane and butene, dichloroethane isomers, cis trans isomerism, ester mass, oxidation of a primary alcohol, percentage yield, bromine addition, an alkene formula from its mass, and the limits of the bromine water test.

Direct answers Answers in order: three, three, two, cis and trans, 17.6 g, 74.0, 69.9 percent, 8.0 g, C5H10, and alkynes also decolourise bromine water.

01 Paper details (check answers afterwards)

Item Detail
Questions 10
Suggested time 20
Difficulty mix Foundation 3 · Intermediate 3 · Challenge 3 · Error redo 1
Chapter Chapter: S6 Chemistry: Organic Reactions and Isomerism
Level S6

02 Questions (10 items)

  1. FoundationHow many structural isomers does pentane C5H12 have?
  2. FoundationHow many structural isomers does butene C4H8 have, counting chain and position differences?
  3. FoundationHow many structural isomers does C2H4Cl2 have?
  4. IntermediateDoes but-2-ene show geometric isomerism, and how many forms are there?
  5. IntermediateWhat mass of ethyl ethanoate, Mr 88.0, forms from 0.20 mol of ethanol with excess ethanoic acid and concentrated sulphuric acid?
  6. IntermediatePropan-1-ol is fully oxidised by acidified dichromate. What is the relative molecular mass of the final product?
  7. ChallengeAn esterification has a theoretical yield of 17.6 g but only 12.3 g is collected. Find the percentage yield.
  8. ChallengeWhat mass of bromine, Mr 160.0, adds to 0.050 mol of propene?
  9. ChallengeAn alkene has relative molecular mass 70.0. Find its molecular formula.
  10. Error redoA student claims that any compound decolourising bromine water must be an alkene. What is wrong?

03 Answers and one-line notes

# Answer One-line note
1 Three They are pentane, 2-methylbutane and 2,2-dimethylpropane, one straight chain and two branched.
2 Three: but-1-ene, but-2-ene and 2-methylpropene A different double bond position or a branched chain gives a different structure.
3 Two: 1,1-dichloroethane and 1,2-dichloroethane Both chlorine atoms on one carbon or one on each carbon gives two different structures.
4 Yes, cis and trans, that is two forms The double bond cannot rotate freely, so the two methyl groups on the same side give cis and on opposite sides give trans.
5 17.6 g The mole ratio is one to one, so 0.20 times 88.0 gives 17.6 g.
6 74.0, propanoic acid A primary alcohol becomes an aldehyde and then a carboxylic acid, and propanoic acid C3H6O2 has mass 74.0.
7 69.9 percent 12.3 divided by 17.6 and multiplied by 100 gives 69.9 percent.
8 8.0 g Each double bond takes one bromine molecule, so 0.050 times 160.0 gives 8.0 g.
9 C5H10 For an alkene 14.0n equals 70.0, so n is five.
10 Alkynes and other unsaturated compounds also decolourise bromine water Fading only shows an unsaturated bond, so the general formula or instrumental analysis is still needed.

04 What to do after marking

  • After marking, redo only the wrong items and write down which step went wrong (formula, unit, or misread number).
  • Repeat the same item two days later; move to the next paper only when both attempts are correct.
  • Parents only need the answer and note columns; there is no need to explain every item.

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